CO2 is a very stable molecule whose conversion is often hindered by kinetic and thermodynamic barriers. Improved catalysts can overcome the kinetic barriers and increase reaction rates, but the thermodynamic equilibrium limits the maximum conversion often to very low levels. To improve the conversion, new techniques to overcome the thermodynamic equilibrium must be developed. CO2Shift project aims to shift reaction equilibrium to the product side in direct synthesis of dimethyl carbonate from CO2 and methanol as a model reaction. The project develops a continuous in-situ equilibrium shift -concept, in which the reaction products are separated already inside the reactor. This leads to improved CO2 conversion and product yield. The main aim of the project is to overcome the thermodynamic limitations by using novel multi-functional absorbent materials and thus enabling feasible industrial operation.

2022

2026